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CAS 5144-89-8 1 10 Phenanthroline Hydrate White Crystalline Powder

Mol No.: 360
Synonymso-Phenanthroline monohydrate; 1,10-Phenanthroline monohydrate
Molecular FormulaC12H8N2.H2O
Molecular Weight198.22
CAS Number5144-89-8
EINECS/ELINCS/
Structure
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Product Details

Properties

AppearanceWhite crystalline powder
Melting Point69-72°C
SolubilityEasy soluble in ethanol and ether, can not be soluble in water
StabilityStable under ordinary conditions

Item
Specification
Appearance
White crystalline powder
Mole Extinction Coefficient of Iron Complex
1.15x104 min
Solubility in Ethanol
Pass
Assay
99.0% min

Application

It's a redox indicator. It also a reagent of testing ferrous ion, palladium, vanadium, cooper, iron and etc.




1,10-Phenanthroline Anhydrous use and synthesis method

Chemical nature

The monohydrate is white crystalline powder. Melting point 93-94℃, melting point of anhydrous substance is 117℃, soluble in 300 parts of water, 70 parts of benzene, soluble in alcohol and acetone. 

Use

It is a common ligand for spectrometric determination of metals and spectroscopic analysis of CO2 reduction. Used in Cu(II)-catalyzed cross-linking reaction of organoboric acid, etc., can also be used as a redox indicator and a reagent for the determination of ferro-titanium. It forms a complex with iron, copper, cobalt, nickel and 2,2'-bipyridine, and forms a red complex with Fe2+. It is oxidized with potassium permanganate to obtain 2,2'-dipyridyl-3,3'-dicarboxylate acid. 

production method

This product can be prepared by heating o-phenylenediamine with glycerol, nitrobenzene and concentrated sulfuric acid, or using 8-aminoquinoline as the raw material. 





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