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Powder White 99% 1 10 Phenanthroline Anhydrous CAS No 66-71-7

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Product Details

Mat no.10007001 1,10-Phenanthroline Anhydrous CAS No.66-71-7 C12H8N2 White Powder Purity≥99%

1,10-Phenanthroline Anhydrous properties

Melting point 114-117 °C(lit.)
Boiling point >330°C
density 1.1836 (rough estimate)
Refractive index 1.5200 (estimate)
Flash point >330°C
Storage conditions Store below +30°C.
Solubility 2.69g/l
form Powder
Acidity coefficient (pKa) 4.84(at 25℃)
color White to light yellow or light pink
Water solubility slightly soluble
Sensitivity Hygroscopic
Merck 14,7214
BRN 126461
stability Stable. Hygroscopic. Store under nitrogen. Incompatible with strong acids, strong oxidizing agents.
InChIKey DGEZNRSVGBDHLK-UHFFFAOYSA-N
CAS database 66-71-7(CAS DataBase Reference)
NIST chemical substance information o-Phenanthroline(66-71-7)
EPA chemical substance information 1,10-Phenanthroline (66-71-7)

 

 

1,10-Phenanthroline Anhydrous use and synthesis method

Chemical nature

The monohydrate is white crystalline powder. Melting point 93-94℃, melting point of anhydrous substance is 117℃, soluble in 300 parts of water, 70 parts of benzene, soluble in alcohol and acetone.

Use

It is a common ligand for spectrometric determination of metals and spectroscopic analysis of CO2 reduction. Used in Cu(II)-catalyzed cross-linking reaction of organoboric acid, etc., can also be used as a redox indicator and a reagent for the determination of ferro-titanium. It forms a complex with iron, copper, cobalt, nickel and 2,2'-bipyridine, and forms a red complex with Fe2+. It is oxidized with potassium permanganate to obtain 2,2'-dipyridyl-3,3'-dicarboxylate acid.

production method

This product can be prepared by heating o-phenylenediamine with glycerol, nitrobenzene and concentrated sulfuric acid, or using 8-aminoquinoline as the raw material.



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